Study on ash deposition under oxyfuel combustion of coal/biomass blends

e-Archivo Repository

Show simple item record

dc.contributor.author Fryda, L.
dc.contributor.author Sobrino, Celia
dc.contributor.author Cieplik, M.
dc.contributor.author Kamp, W.L. van de
dc.date.accessioned 2012-03-02T09:50:07Z
dc.date.available 2012-03-02T09:50:07Z
dc.date.issued 2010-08
dc.identifier.bibliographicCitation Fuel, (2010), 89(8), 1889-1902
dc.identifier.issn 0016-2361
dc.identifier.uri http://hdl.handle.net/10016/13614
dc.description.abstract Combustion in an O₂/CO₂mixture (oxyfuel) has been recognized as a promising technology for CO₂capture as it produces a high CO₂concentration flue gas. Furthermore, biofuels in general contribute to CO₂reduction in comparison with fossil fuels as they are considered CO₂neutral. Ash formation and deposition (surface fouling) behavior of coal/biomass blends under O₂/CO₂combustion conditions is still not extensively studied. Aim of this work is the comparative study of ash formation and deposition of selected coal/biomass blends under oxyfuel and air conditions in a lab scale pulverized coal combustor (drop tube). The fuels used were Russian and South African coals and their blends with Shea meal (cocoa). A horizontal deposition probe, equipped with thermocouples and heat transfer sensors for on line data acquisition, was placed at a fixed distance from the burner in order to simulate the ash deposition on heat transfer surfaces (e.g. water or steam tubes). Furthermore, a cascade impactor (staged filter) was used to obtain size distributed ash samples including the submicron range at the reactor exit. The deposition ratio and propensity measured for the various experimental conditions were higher in all oxyfuel cases. The SEM/EDS and ICP analyses of the deposit and cascade impactor ash samples indicate K interactions with the alumina silicates and to a smaller extend with Cl, which was all released in the gas phase, in both the oxyfuel and air combustion samples. Sulfur was depleted in both the air or oxyfuel ash deposits. S and K enrichment was detected in the fine ash stages, slightly increased under air combustion conditions. Chemical equilibrium calculations were carried out to facilitate the interpretation of the measured data; the results indicate that temperature dependence and fuels/blends ash composition are the major factors affecting gaseous compounds and ash composition rather than the combustion environment, which seems to affect the fine ash (submicron) ash composition, and the ash deposition mechanisms
dc.description.sponsorship The research work reported in this paper was partly carried out with the financial support from the RFCS contract number RFCRCT- 2006-00010. The very fine work done by Peter Heere in carrying out the experiments is highly acknowledged
dc.format.mimetype application/pdf
dc.language.iso eng
dc.publisher Elsevier
dc.rights © Elsevier
dc.subject.other Oxyfuel
dc.subject.other Ash deposition
dc.subject.other SEM/EDS
dc.subject.other Cascade impactor
dc.title Study on ash deposition under oxyfuel combustion of coal/biomass blends
dc.type article
dc.description.status Publicado
dc.relation.publisherversion http://dx.doi.org/10.1016/j.fuel.2009.11.022
dc.subject.eciencia Ingeniería Industrial
dc.subject.eciencia Física
dc.identifier.doi 10.1016/j.fuel.2009.11.022
dc.rights.accessRights openAccess
dc.type.version acceptedVersion
dc.identifier.publicationfirstpage 1889
dc.identifier.publicationissue 8
dc.identifier.publicationlastpage 1902
dc.identifier.publicationvolume Fuel
dc.identifier.publicationvolume 89
 Find Full text

Files in this item

*Click on file's image for preview. (Embargoed files's preview is not supported)


This item appears in the following Collection(s)

Show simple item record