Publication:
The electrochemical kinetics of cerium selenide nano-pebbles: The design of a device-grade symmetric configured wide-potential flexible solid-state supercapacitor

dc.affiliation.dptoUC3M. Departamento de Ciencia e Ingeniería de Materiales e Ingeniería Químicaes
dc.affiliation.grupoinvUC3M. Grupo de Investigación: Materiales compuestos poliméricos e interfaseses
dc.contributor.authorPandit, Bidhan
dc.contributor.authorAgarwal, Akanksha
dc.contributor.authorPatel, Priyanka
dc.contributor.authorSankapal, Babasaheb R.
dc.date.accessioned2023-01-17T08:30:47Z
dc.date.available2023-01-17T08:30:47Z
dc.date.issued2021-02-21
dc.description.abstractNext-generation portable flexible electronic appliances require liquid-free energy storage supercapacitor devices to eliminate leakage and to support mechanical bending that is compatible with roll-to-roll technologies. Hence, a state-of-the-art process is presented to design a solid-state, wide-potential and flexible supercapacitor through the use of nano-pebbles of cerium selenide via a simple successive ionic layer adsorption and reaction (SILAR) method that could allow an industry scalable route. We strongly believe that this is the first approach amongst physical and chemical routes not only for synthesizing cerium selenide in thin-film form but also using it for device-grade supercapacitor applications. The designed solid-state symmetric supercapacitor assembled from cerium selenide electrodes sandwiched by PVA–LiClO4 gel electrolyte attains a wide potential window of 1.8 V with capacitance of 48.8 F g−1 at 2 mV s−1 and reveals excellent power density of 4.89 kW kg−1 at an energy density of 11.63 W h kg−1. The formed device is capable of 87% capacitive retention even at a mechanical bending angle of 175°. Lighting up a strip of 21 parallel connected red LEDs clearly demonstrates the practical use of the designed symmetric solid-state supercapacitor, aiming towards the commercialization of the product in the future.en
dc.description.sponsorshipThe authors gratefully acknowledge DST/TMD/MES/2k16/09 project, Government of India.en
dc.format.extent10es
dc.identifier.bibliographicCitationPandit, B., Agarwal, A., Patel, P., & Sankapal, B. R. (2021). The electrochemical kinetics of cerium selenide nano-pebbles: the design of a device-grade symmetric configured wide-potential flexible solid-state supercapacitor. Nanoscale Advances, 3(4), 1057–1066.en
dc.identifier.doihttps://doi.org/10.1039/d0na00893a
dc.identifier.issn2516-0230
dc.identifier.publicationfirstpage1057es
dc.identifier.publicationissue4es
dc.identifier.publicationlastpage1066es
dc.identifier.publicationtitleNanoscale Advancesen
dc.identifier.publicationvolume3es
dc.identifier.urihttps://hdl.handle.net/10016/36278
dc.identifier.uxxiAR/0000029643
dc.language.isoengen
dc.publisherRoyal Society of Chemistryen
dc.rights© 2021 The Author(s). Published by the Royal Society of Chemistryen
dc.rightsThis article is Open Accessen
dc.rightsAtribución 3.0 España*
dc.rights.accessRightsopen accessen
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.subject.ecienciaMaterialeses
dc.titleThe electrochemical kinetics of cerium selenide nano-pebbles: The design of a device-grade symmetric configured wide-potential flexible solid-state supercapacitoren
dc.typeresearch article*
dc.type.hasVersionVoR*
dspace.entity.typePublication
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