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Cyclodextrin-Grafted TiO2 Nanoparticles: Synthesis, Complexation Capacity, and Dispersion in Polymeric Matrices

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dc.affiliation.dptoUC3M. Departamento de Ciencia e Ingeniería de Materiales e Ingeniería Químicaes
dc.affiliation.grupoinvUC3M. Grupo de Investigación: Polímeros y Compositeses
dc.contributor.authorMonreal-Pérez, Pablo
dc.contributor.authorIsasi, José Ramón
dc.contributor.authorGonzález Benito, Francisco Javier
dc.contributor.authorOlmos Díaz, Dania
dc.contributor.authorGonzalez Gaitano, Gustavo
dc.date.accessioned2019-02-07T10:10:28Z
dc.date.available2019-02-07T10:10:28Z
dc.date.issued2018-08-22
dc.description.abstractThe modification of the surface of titanium dioxide nanoparticles (TiO2 NPs) by the incorporation of cyclodextrins (CDs), cyclic oligosaccharides with a hydrophobic cavity, can largely improve the functionality of TiO2 by lodging molecules of interest in the CD to act directly on the surface of the nanoparticles or for further release. With this aim, we have synthesized betaCD-modified nanoparticles (betaCDTiO2 NPs) by a two-step reaction that involves the incorporation of a spacer and then the linking of the macrocycle, and characterized them by thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). The capacity of the functionalized structures to trap model compounds (Rhodamine and 1-naphthol) has been compared to that of bare TiO2 NPs by fluorescence and Ultraviolet-visible (UV-visible) spectroscopy. The presence of the CDs on the surface of the TiO2 avoids the photo-degradation of the guest, which is of interest in order to combine the photocatalytic activity of TiO2, one of its most interesting features for practical purposes, with the delivery of compounds susceptible of being photo-degraded. The betaCDTiO2 NPs have been dispersed in polymeric matrices of frequently used polymers, polyethylene (LDPE) and polyethylene oxide (PEO), by cryogenic high energy ball milling to produce nanocomposites in the form of films. The surface modification of the nanoparticles favors the homogenization of the filler in the matrix, while the nanoparticles, either in bare or functionalized form, do not seem to alter the crystallization properties of the polymer at least up to a 5% (w/w) load of filler.es
dc.description.sponsorshipThis research was funded by Ministerio de Ciencia e Innovación, project MAT2014-59116-C2-2-R.es
dc.format.extent16es
dc.format.mimetypeapplication/pdf
dc.identifier.bibliographicCitationMonreal-Pérez, P., Isasi, J.R., González-Benito, J., Olmos, D., González-Gaitano, G. (2018). Cyclodextrin-Grafted TiO2 Nanoparticles: Synthesis, Complexation Capacity, and Dispersion in Polymeric Matrices. Nanomaterials, 8 (9), 642.es
dc.identifier.doihttps://doi.org/10.3390/nano8090642
dc.identifier.issn2079-4991
dc.identifier.publicationissue9es
dc.identifier.publicationtitleNanomaterialses
dc.identifier.publicationvolume8es
dc.identifier.urihttps://hdl.handle.net/10016/28009
dc.identifier.uxxiAR/0000022432
dc.language.isoenges
dc.publisherMDPIes
dc.relation.projectIDGobierno de España. MAT2014-59116-C2-2-Res
dc.rights© 2018 by the authors; licensee MDPI, Basel, Switzerland.es
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.accessRightsopen accesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subject.ecienciaQuímicaes
dc.subject.ecienciaMaterialeses
dc.subject.otherTiO2 nanoparticleses
dc.subject.otherCyclodextrinses
dc.subject.otherPolymer nanocompositeses
dc.subject.otherSurface modificationes
dc.subject.otherHigh energy ball milling (HEBM)es
dc.titleCyclodextrin-Grafted TiO2 Nanoparticles: Synthesis, Complexation Capacity, and Dispersion in Polymeric Matriceses
dc.typeresearch article*
dc.type.hasVersionVoR*
dspace.entity.typePublication
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