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Vapor−Liquid Equilibria and Excess Properties of Cyclohexane−1,1-Dimethylpropyl Methyl Ether (TAME) Mixtures

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dc.affiliation.dptoUC3M. Departamento de Neurociencia y Ciencias Biomédicas
dc.contributor.authorRío Hernández, Armando del
dc.contributor.authorCoto, Baudilio
dc.contributor.authorPando, Concepción
dc.contributor.authorRenuncio, Juan A. R.
dc.contributor.funderMinisterio de Educación, Cultura y Deporte (España)
dc.date.accessioned2024-07-23T08:36:54Z
dc.date.available2024-07-23T08:36:54Z
dc.date.issued2001-01-01
dc.description.abstractVapor−liquid equilibrium (VLE) data are reported for the binary mixtures formed by cyclohexane and the branched ether 1,1-dimethylpropyl methyl ether (tert-amyl methyl ether or TAME). A Gibbs−Van Ness type apparatus was used to obtain total vapor pressure measurements for cyclohexane−TAME mixtures as a function of composition at 298.15, 308.15, 318.15, and 328.15 K. These data are analyzed together with isothermal VLE data previously obtained at 313.15 K and excess enthalpies and volumes previously determined at 298.15 K for these mixtures. The Peng−Robinson equation of state and the Wong−Sandler mixing rule, the lattice-fluid (LF) model, the Flory theory, the UNIQUAC model, and the modified UNIFAC (Dortmund) model are used to correlate or predict the VLE data and excess properties of cyclohexane−TAME mixtures.
dc.description.sponsorshipThis work was funded by the Spanish Ministry of Education, DGICYT PB97-315, 1998−2000. A. del Río acknowledges the Comunidad Autonoma de Madrid for its support through a predoctoral grant.
dc.format.extent7
dc.identifier.bibliographicCitationdel Río, A., Coto, B., Pando, C., & Renuncio, J. A. R. (2001). Vapor−Liquid equilibria and excess properties of Cyclohexane−1,1-dimethylpropyl methyl ether (TAME) mixtures. Industrial & Engineering Chemistry Research, 40(2), 689–695.
dc.identifier.issn1520-5045
dc.identifier.publicationfirstpage689
dc.identifier.publicationissue2
dc.identifier.publicationlastpage695
dc.identifier.publicationtitleIndustrial & Engineering Chemistry Research
dc.identifier.publicationvolume40
dc.identifier.urihttps://hdl.handle.net/10016/44203
dc.language.isoeng
dc.publisherACS Publications
dc.relation.projectIDGobierno de España. DGICYT PB97-315
dc.relation.publisherversionhttps://doi.org/10.1021/ie0006514
dc.rights© 2001 American Chemical Society
dc.rights.accessRightsopen access
dc.subject.ecienciaBiología y Biomedicina
dc.titleVapor−Liquid Equilibria and Excess Properties of Cyclohexane−1,1-Dimethylpropyl Methyl Ether (TAME) Mixtures
dc.typeresearch article
dc.type.hasVersionAM
dspace.entity.typePublication
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