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Obtaining medical textiles based on viscose and chitosan/zinc nanoparticles with improved antibacterial properties by using a dielectric barrier discharge

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Abstract
This study aimed to obtain functional viscose textiles based on chitosan coatings with improved antibacterial properties and washing durability. For that reason, before functionalization with chitosan/zinc nanoparticles (NCH+Zn), the viscose fabric was modified by nonthermal gas plasma of dielectric barrier discharge (DBD) to introduce into its structure functional groups suitable for attachment of NCH+Zn. NCH+Zn were characterized by measurements of hydrodynamic diameter and zeta potential and AFM. DBD-plasma-modified and NCH+Zn-functionalized fabrics were characterized by zeta potential measurements, ATR-FTIR spectroscopy, the calcium acetate method (determination of content of carboxyl and aldehyde groups), SEM, breaking-strength measurements, elemental analysis, and ICP-OES. Their antibacterial activity was determined under dynamic contact conditions. In addition to SEM, the NCH+Zn distributions on viscose fabrics were also indirectly characterized by measuring their absorbent capacities before and after functionalization with NCH+Zn. Washing durability was monitored through changes in the zeta potential, chitosan and zinc content, and antibacterial activity after 1, 3, and 5 washing cycles. The obtained results showed that DBD plasma modification contributed to the simultaneous improvement of NCH+Zn sorption and antibacterial properties of the viscose fabric functionalized with NCH+Zn, and its washing durability, making it suitable for the production of high-value-added medical textiles.
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This article belongs to the Special Issue Develop Antimicrobial Polymer Textiles for Medical Applications
Keywords
Antibacterial Properties, Chitosan/Zinc Nanoparticles, Dielectric Barrier Discharge, Medical Textiles, Viscose
Bibliographic citation
Korica, M., Kramar, A., Fratnik, Z. P., Obradović, B. M., Kuraica, M. M., Dojčinović, B., Zemljič, L. F., & Kostic, M. (2022). Obtaining Medical Textiles Based on Viscose and Chitosan/Zinc Nanoparticles with Improved Antibacterial Properties by Using a Dielectric Barrier Discharge. Polymers, 14(19), 4152.