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Vapour–liquid equilibria for the binary system cyclohexane–1,1-dimethylethyl methyl ether (MTBE) at 298.15, 308.15 and 318.15 K

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dc.affiliation.dptoUC3M. Departamento de Neurociencia y Ciencias Biomédicas
dc.contributor.authorRío Hernández, Armando del
dc.contributor.authorCoto, Baudilio
dc.contributor.authorPando, Concepción
dc.contributor.authorRenuncio, Juan A. R.
dc.contributor.funderMinisterio de Educación, Cultura y Deporte (España)
dc.date.accessioned2024-07-23T07:53:05Z
dc.date.available2024-07-23T07:53:05Z
dc.date.issued1999-11
dc.description.abstractVapour–liquid equilibrium data are reported for the binary mixtures formed by cyclohexane and the branched ether 1,1-dimethylethyl methyl ether (tert-butyl methyl ether or MTBE). A Gibbs–Van Ness type apparatus was used to obtain total vapour pressure measurements for cyclohexane–MTBE mixtures at 298.15, 308.15 and 318.15 K. The system exhibits very small deviations from Raoult's law with a nearly ideal behaviour. No temperature effect on vapour compositions is observed. Results are analysed in terms of the Peng–Robinson equation of state and the Wong–Sandler mixing rule, the lattice-fluid model, the UNIQUAC model, and the UNIFAC and modified UNIFAC models.
dc.description.sponsorshipThis work was funded by the Spanish Ministry of Education, DGICYT PB97-315, 1998È2000. A. del Ri o acknowledges the Comunidad Autonoma de Madrid for its support through a predoctoral grant.
dc.format.extent4
dc.identifier.bibliographicCitationdel Río, A., Coto, B., Pando, C., & Renuncio, J. A. R. (1999). Vapour–liquid equilibria for the binary system cyclohexane–1,1-dimethylethyl methyl ether (MTBE) at 298.15, 308.15 and 318.15 K. Physical chemistry chemical physics: PCCP, 1(21), 4995–4998.
dc.identifier.issn1463-9084
dc.identifier.publicationfirstpage4995
dc.identifier.publicationissue21
dc.identifier.publicationlastpage4998
dc.identifier.publicationtitlePhysical chemistry chemical physics
dc.identifier.urihttps://hdl.handle.net/10016/44200
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.projectIDGobierno de España. DGICYT PB97-315
dc.relation.publisherversionhttps://doi.org/10.1039/A906301C
dc.rights© The Owner Societies 1999
dc.rights.accessRightsopen access
dc.subject.ecienciaBiología y Biomedicina
dc.titleVapour–liquid equilibria for the binary system cyclohexane–1,1-dimethylethyl methyl ether (MTBE) at 298.15, 308.15 and 318.15 K
dc.typeresearch article
dc.type.hasVersionAM
dspace.entity.typePublication
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