Publication:
Reduction of Grain Boundary Resistance of La0.5Li0.5TiO3 by the Addition of Organic Polymers

dc.affiliation.dptoUC3M. Departamento de Ciencia e Ingeniería de Materiales e Ingeniería Químicaes
dc.affiliation.grupoinvUC3M. Grupo de Investigación: Síntesis y Procesado de Materialeses
dc.contributor.authorBoyano, Iker
dc.contributor.authorMainar, Aroa R.
dc.contributor.authorBlázquez, Alberto
dc.contributor.authorKvasha, Andriy
dc.contributor.authorBengoechea, Miguel
dc.contributor.authorDe Meatza, Iratxe
dc.contributor.authorGarcía Martín, Susana
dc.contributor.authorLumbier Álvarez, Alejandro
dc.contributor.authorSanz, Jesus
dc.contributor.authorGarcía Alvarado, Flaviano
dc.contributor.funderMinisterio de Educación y Ciencia (España)es
dc.contributor.funderMinisterio de Ciencia e Innovación (España)es
dc.date.accessioned2021-05-04T09:59:55Z
dc.date.available2021-05-04T09:59:55Z
dc.date.issued2021-01
dc.description.abstractThe organic solvents that are widely used as electrolytes in lithium ion batteries present safety challenges due to their volatile and flammable nature. The replacement of liquid organic electrolytes by non-volatile and intrinsically safe ceramic solid electrolytes is an effective approach to address the safety issue. However, the high total resistance (bulk and grain boundary) of such compounds, especially at low temperatures, makes those solid electrolyte systems unpractical for many applications where high power and low temperature performance are required. The addition of small quantities of a polymer is an efficient and low cost approach to reduce the grain boundary resistance of inorganic solid electrolytes. Therefore, in this work, we study the ionic conductivity of different composites based on non-sintered lithium lanthanum titanium oxide (La0.5Li0.5TiO3) as inorganic ceramic material and organic polymers with different characteristics, added in low percentage (<15 wt.%). The proposed cheap composite solid electrolytes double the ionic conductivity of the less cost-effective sintered La0.5Li0.5TiO3.en
dc.description.sponsorshipWe thank the Spanish Ministry for Science and Technology (MAT2007-64486-C07-05) and CDTI (ALMAGRID of the "CERVERA Centros Tecnológicos" program, CER-20191006) for financial their support. JS, AV, SG, and FG also want to acknowledge Agencia Española de Investigación /Fondo Europeo de Desarrollo Regional (FEDER/UE) for funding the projects PID2019-106662RB-C41, C42, C43, and C44.en
dc.format.extent12
dc.identifier.bibliographicCitationBoyano, I., Mainar, A. R., Blázquez, J. A., Kvasha, A., Bengoechea, M., de Meatza, I., García-Martín, S., Varez, A., Sanz, J. & García-Alvarado, F. (2020). Reduction of Grain Boundary Resistance of La0.5Li0.5TiO3 by the Addition of Organic Polymers. Nanomaterials, 11(1), 61.en
dc.identifier.doihttps://doi.org/10.3390/nano11010061
dc.identifier.issn2079-4991
dc.identifier.publicationfirstpage1
dc.identifier.publicationissue1
dc.identifier.publicationlastpage12
dc.identifier.publicationtitleNanomaterialsen
dc.identifier.publicationvolume11
dc.identifier.urihttps://hdl.handle.net/10016/32525
dc.identifier.uxxiAR/0000027166
dc.language.isoeng
dc.publisherMDPI
dc.relation.projectIDGobierno de España. MAT2007-64486-C07-05es
dc.relation.projectIDGobierno de España. PID2019-106662RB-C41es
dc.relation.projectIDGobierno de España. PID2019-106662RB-C42es
dc.relation.projectIDGobierno de España. PID2019-106662RB-C43es
dc.relation.projectIDGobierno de España. PID2019-106662RB-C44es
dc.rights© 2020 by the authors.en
dc.rightsAtribución 3.0 España*
dc.rights.accessRightsopen access
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.subject.ecienciaMaterialeses
dc.subject.otherLithium Lanthanum Titanium Oxide (LLTO)en
dc.subject.otherGrain boundary resistanceen
dc.subject.otherSolid ceramic-polymer composite electrolyteen
dc.subject.otherLithium ion conductivityen
dc.titleReduction of Grain Boundary Resistance of La0.5Li0.5TiO3 by the Addition of Organic Polymersen
dc.typeresearch article*
dc.type.hasVersionVoR*
dspace.entity.typePublication
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