Publication: Reduction of Grain Boundary Resistance of La0.5Li0.5TiO3 by the Addition of Organic Polymers
dc.affiliation.dpto | UC3M. Departamento de Ciencia e Ingeniería de Materiales e Ingeniería Química | es |
dc.affiliation.grupoinv | UC3M. Grupo de Investigación: Síntesis y Procesado de Materiales | es |
dc.contributor.author | Boyano, Iker | |
dc.contributor.author | Mainar, Aroa R. | |
dc.contributor.author | Blázquez, Alberto | |
dc.contributor.author | Kvasha, Andriy | |
dc.contributor.author | Bengoechea, Miguel | |
dc.contributor.author | De Meatza, Iratxe | |
dc.contributor.author | García Martín, Susana | |
dc.contributor.author | Lumbier Álvarez, Alejandro | |
dc.contributor.author | Sanz, Jesus | |
dc.contributor.author | García Alvarado, Flaviano | |
dc.contributor.funder | Ministerio de Educación y Ciencia (España) | es |
dc.contributor.funder | Ministerio de Ciencia e Innovación (España) | es |
dc.date.accessioned | 2021-05-04T09:59:55Z | |
dc.date.available | 2021-05-04T09:59:55Z | |
dc.date.issued | 2021-01 | |
dc.description.abstract | The organic solvents that are widely used as electrolytes in lithium ion batteries present safety challenges due to their volatile and flammable nature. The replacement of liquid organic electrolytes by non-volatile and intrinsically safe ceramic solid electrolytes is an effective approach to address the safety issue. However, the high total resistance (bulk and grain boundary) of such compounds, especially at low temperatures, makes those solid electrolyte systems unpractical for many applications where high power and low temperature performance are required. The addition of small quantities of a polymer is an efficient and low cost approach to reduce the grain boundary resistance of inorganic solid electrolytes. Therefore, in this work, we study the ionic conductivity of different composites based on non-sintered lithium lanthanum titanium oxide (La0.5Li0.5TiO3) as inorganic ceramic material and organic polymers with different characteristics, added in low percentage (<15 wt.%). The proposed cheap composite solid electrolytes double the ionic conductivity of the less cost-effective sintered La0.5Li0.5TiO3. | en |
dc.description.sponsorship | We thank the Spanish Ministry for Science and Technology (MAT2007-64486-C07-05) and CDTI (ALMAGRID of the "CERVERA Centros Tecnológicos" program, CER-20191006) for financial their support. JS, AV, SG, and FG also want to acknowledge Agencia Española de Investigación /Fondo Europeo de Desarrollo Regional (FEDER/UE) for funding the projects PID2019-106662RB-C41, C42, C43, and C44. | en |
dc.format.extent | 12 | |
dc.identifier.bibliographicCitation | Boyano, I., Mainar, A. R., Blázquez, J. A., Kvasha, A., Bengoechea, M., de Meatza, I., García-Martín, S., Varez, A., Sanz, J. & García-Alvarado, F. (2020). Reduction of Grain Boundary Resistance of La0.5Li0.5TiO3 by the Addition of Organic Polymers. Nanomaterials, 11(1), 61. | en |
dc.identifier.doi | https://doi.org/10.3390/nano11010061 | |
dc.identifier.issn | 2079-4991 | |
dc.identifier.publicationfirstpage | 1 | |
dc.identifier.publicationissue | 1 | |
dc.identifier.publicationlastpage | 12 | |
dc.identifier.publicationtitle | Nanomaterials | en |
dc.identifier.publicationvolume | 11 | |
dc.identifier.uri | https://hdl.handle.net/10016/32525 | |
dc.identifier.uxxi | AR/0000027166 | |
dc.language.iso | eng | |
dc.publisher | MDPI | |
dc.relation.projectID | Gobierno de España. MAT2007-64486-C07-05 | es |
dc.relation.projectID | Gobierno de España. PID2019-106662RB-C41 | es |
dc.relation.projectID | Gobierno de España. PID2019-106662RB-C42 | es |
dc.relation.projectID | Gobierno de España. PID2019-106662RB-C43 | es |
dc.relation.projectID | Gobierno de España. PID2019-106662RB-C44 | es |
dc.rights | © 2020 by the authors. | en |
dc.rights | Atribución 3.0 España | * |
dc.rights.accessRights | open access | |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.subject.eciencia | Materiales | es |
dc.subject.other | Lithium Lanthanum Titanium Oxide (LLTO) | en |
dc.subject.other | Grain boundary resistance | en |
dc.subject.other | Solid ceramic-polymer composite electrolyte | en |
dc.subject.other | Lithium ion conductivity | en |
dc.title | Reduction of Grain Boundary Resistance of La0.5Li0.5TiO3 by the Addition of Organic Polymers | en |
dc.type | research article | * |
dc.type.hasVersion | VoR | * |
dspace.entity.type | Publication |
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