RT Journal Article
T1 An efficient method for the carboxylation of few-wall carbon nanotubes with little damage to their sidewalls
A1 Martín Cádiz, Olga
A1 Gutierrez, Humberto R.
A1 Maroto Valiente, Ángel
A1 Terrones Maldonado, Mauricio
A1 Blanco, Tamara
A1 Baselga Llidó, Juan
AB We report a novel method that is able to efficiently functionalize carbon nanotubes (few-walled: from 1 to 6 layers and multiwalled) with a high yield of carboxyl groups, based on treatments with H₂O₂ in the presence of UV light. The amount of carboxylic groups was quantified by X-ray photoelectron spectroscopy and back-titration, showing both measurements reasonable agreement. According to the zeta potential values and to the amount of suspended nanotubes, we demonstrate that the method is able to produce uniform and stable suspensions of carbon nanotubes in water. With the aid of scanning and transmission electron microscopy, thermogravimetric analysis, and Raman spectroscopy, we show that the surfaces of the tubes are not damaged by the treatment and that the functionalized tubes have an enhanced reactivity toward oxygen. This route is efficient and could now be used to fabricate polymer composites using few-walled and multiwalled carbon nanotubes.
PB Elsevier
SN 0254-0584
YR 2013
FD 2013-07-15
LK https://hdl.handle.net/10016/25994
UL https://hdl.handle.net/10016/25994
LA eng
NO O. Martín and J. Baselga acknowledge support from Ministerio de Ciencia e Innovación (Spain) under grants MAT2010-17091 and MAT2009-06296E. M. Terrones acknowledges support from the Research Center for Exotic Nanocarbons, Japan regional Innovation Strategy Program by the Excellence, JST. T. Blanco acknowledges support from CDTI under the project NANOMULFUN (SAE-20081035).
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RD 1 sept. 2024