RT Journal Article
T1 High mass loading additive-free LiFePO[subíndice 4] cathodes with 500 μm thickness for high areal capacity Li-ion batteries
A1 Torre Gamarra, Carmen de la
A1 Sotomayor Lozano, María Eugenia
A1 Sánchez, Jean Yves
A1 Levenfeld Laredo, Belén
A1 Varez, Alejandro
A1 Laïk, Barbara
A1 Pereira Ramos, Jean-Pierre
AB We report the preparation of thick ceramic electrodes of the olivine LiFePO4 (LFP) with high mass loading. These electrodes are preparated by means of Powder Extrusion Moulding (PEM), which is a technology easily scalable and cheap. These LFP cathodes are additive-free (neither binder nor extra carbon black) with ~0.5 mm thickness, allowing to develop very high areal capacity (13.7 mA h cm−2). By means of a strict control of sintering process, the carbon coating of the commercial LFP powder remains and the decomposition of the active material is prevented. The optimized self-supported LFP cathode presents good cyclability over 20 cycles at C/10 with no capacity loss. The good electrochemical performance of these novel LFP thick electrodes and their non-flammability make them interesting candidates for both mobile and stationary applications.
PB Elsevier
SN 0378-7753
YR 2020
FD 2020-05-15
LK https://hdl.handle.net/10016/31884
UL https://hdl.handle.net/10016/31884
LA eng
NO Authors would like to thank financial support received from Spanish Government MICINN (MAT2016-78362-C4-3-R project), and Madrid regional Government (MATERYENER3CM S2013/MIT-2753 program). They also thank the ICTS-Centro Nacional de Microscopía Electrónica (UCM, Madrid) for instrumental facilities and Dr. Esteban Urones for fruitful discussion about carbon coating. J.-Y. Sanchez acknowledges the CONEX Programme, funding received from Universidad Carlos III de Madrid, the European Union's Seventh Framework Programme for research, technological development and demonstration (Grant agreement n. 600371), Spanish Ministry of Economy and Competitiveness (COFUND2013-40258) and Banco Santander. C. de la Torre-Gamarra would like to thank Universidad Carlos III de Madrid for the mobility grant received for her predoctoral stay at Institut de Chimie et des Matériaux Paris Est (Thiais – France).
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RD 1 sept. 2024