RT Journal Article
T1 Immobilized Ni on TMEDA@βiO2@aSiO2@Fe3O4: as a novel magnetic nanocatalyst for preparation of pyrido[2,3-d:6,5-d']dipyrimidines
A1 Almajidi, Yasir Qasim
A1 Ubaidullah, Mohd
A1 Pandit, Bidhan
A1 Kareem, A. K.
A1 Romero Parra, Rosario Mireya
A1 Bobirjon, Adizov
A1 Kadhum, Wesam R.
A1 Al-Erjan, Amran M.
A1 Abosaooda, Munther
A1 Mahmoud, Aisha Kamal
AB In the current body of research, a very quick and effectual procedure for the synthesis of pyrido[2,3-d:6,5-d']dipyrimidines has been developed. This method is accomplished through the one-pot multi-component reaction of 2-thiobarbituric acid, NH4OAc and aldehydes utilizing Ni-TMEDA@βSiO2@αSiO2@Fe3O4 as a novel mesoporous nanomagnetic catalyst at room temperature. This protocol is one of the few reports of the preparation of these derivatives without the use of conventional heating as well as energies such as microwave and ultrasound radiation. The characterization of the prepared catalyst was well accomplished by different techniques such as FT-IR, ICP-OES, SEM, TEM, BET, XRD, VSM, TGA, EDX and Elemental mapping. This organometallic catalyst was reusable for seven times with negligible decrement in its catalytic performance. In addition, all of the products were produced with high TON and TOF values, which demonstrates that our catalyst has a very high level of activity in the preparation of pyrido[2,3-d:6,5-d']dipyrimidines.
PB Royal Society of Chemistry
SN 2046-2069
YR 2023
FD 2023-04-14
LK https://hdl.handle.net/10016/39122
UL https://hdl.handle.net/10016/39122
LA eng
NO Correction, Published: 06 June 2023, in RSC Advances, 2023, 13 (25), p.16984. https://doi.org/10.1039/d3ra90048g
DS e-Archivo
RD 1 jul. 2024