RT Journal Article T1 Positron annihilation study of defect distribution in 8YSZ nanostructure A1 Gonzalo-Juan, Isabel A1 Parente, Paola A1 Sánchez-Herencia, A. J. A1 Rubio, Fausto A1 Pareja Pareja, Ramiro A1 Ferrari, Begoña AB The impact of the interfacial contribution on overall properties increases with decreasing grain size of polycrystalline materials. It is well known that distribution and size of cluster defects are rather different in bulk than grain boundaries. In light of "bottom-up" approaches, a study at the atomic level determining the distribution of crystallographic defects could clarify their contribution to the macroscopic properties, and then differentiate materials for outstanding or precise applications. In this work, Positron Annihilation Spectroscopy (PAS) is used to characterize the distribution of defects within 8 mol% Y₂O₃-stabilized zirconia (8YSZ) structures prepared by sintering through three different thermal treatments, i.e. a conventional thermal cycle in air and N₂/H₂ atmosphere, and a fast firing cycle in air, which lead to average grain sizes < 260 nm. PB Elsevier SN 0167-2738 YR 2011 FD 2011-05 LK https://hdl.handle.net/10016/19786 UL https://hdl.handle.net/10016/19786 LA eng NO The authors would like to acknowledge the financial support from the Spanish Government through the projects MAT2009-14448-C02-01 and IPT-310000-2010-12. DS e-Archivo RD 28 may. 2024