RT Journal Article
T1 Reactions of [60]fullerene with alkynes promoted by OH−
A1 Chang, Wei-Wei
A1 He, Fa-Gui
A1 García Peñas, Alberto
A1 Shekh, Mehdihasan I.
A1 Li, Zong-Jun
AB In the current work, the reactions of [60]fullerene with alkynes promoted by OH− (base) are addressed. The treatment of C60 with alkynes in the presence of TBAOH produces alkynylation products (R-C60–H) with high selectivity in o-DCB at 100 °C. Plausible reaction mechanisms were proposed. This work provides a convenient and environmental friendly method for the functionalization of fullerenes.
PB Royal Society of Chemistry
SN 2046-2069
YR 2022
FD 2022
LK https://hdl.handle.net/10016/37097
UL https://hdl.handle.net/10016/37097
LA eng
NO Correction: The authors regret that the name of one of the authors (Fa-Gui He) was shown incorrectly in the original article. The corrected author list is as shown above. The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers. (RSC Adv., 2022, 12, 15740)
NO This work was supported by the Natural Science Foundation of Shandong Province in China (BS2015CL011 for WWC) and the National Natural Science Foundation of China (21202157 for ZJL). The authors gratefully acknowledge the financial support of the China Scholarship Council (CSC), PRC, and German Academic Exchange Service (DAAD), Germany. We thank Dr Wang Shentang (School of Chemistry and Chemical Engineering, and Chongqing Key Laboratory of Soft-Matter Material Chemistry and Function Manufacturing, Southwest University, Chongqing 400715, PR China) for help with the refinement of crystal structure.
DS e-Archivo
RD 18 jul. 2024