Design, fabrication and characterization of microreactors for high temperature syntheses

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dc.contributor.author Martínez Cisneros, Cynthia Susana
dc.contributor.author Gómez dePedro, Sara
dc.contributor.author Puyol, Mar
dc.contributor.author García García, Joan
dc.contributor.author Alonso Chamarro, Julián
dc.date.accessioned 2018-04-13T08:35:55Z
dc.date.accessioned 2018-05-03T15:05:42Z
dc.date.available 2018-05-03T15:05:42Z
dc.date.issued 2012-11-15
dc.identifier.bibliographicCitation Martínez-Cisneros, C.S., Gómez-dePedro, S., Puyol, M., García-García, J., Alonso-Chamarro, J. (2012). Design, fabrication and characterization of micorreactors for high temperatures syntheses. Chemical Engineering Journal, 211-212, pp.432-441.
dc.identifier.issn 1385-8947
dc.identifier.uri http://hdl.handle.net/10016/26635
dc.description.abstract Microfluidic reactors offer many potential advantages in several research and industrial fields such as processes intensification, which includes a better reaction control (kinetics and thermodynamics), a high throughput and a safer operational environment (reduced manipulation of dangerous reagents and low sub-products generation). Nevertheless, scaling-down limitations appear concerning the materials used in the fabrication of microreactors for most of the liquid-phase reactions, since they usually require high temperatures (up to 300 °C), solvents and organic reagents. In this work, the development of a set of modular and monolithic microreactors based on the integration of microfluidics and a thermal platform (sensor/high-temperature heater) is proposed to perform high temperature reactions. The reliability and performance of both configurations were evaluated through an exhaustive characterization process regarding their thermal and microfluidic performance. Obtained results make the devices viable for their application in controlled and reproducible synthetic processes occurring at high temperatures such as the synthesis of quantum dots. The proposed microfluidic approach emerge as an engaging tool for processes intensification, since it provides better mass and temperature transfer than conventional methods with a reduction not only of the size and energy consumption, but also of by-products and reagents consumption.
dc.description.sponsorship This work has been supported by the Spanish Ministry of Science and Innovation (MICINN) through projects CTQ2009-12128 and the Consolider Ingenio 2010 project CSD2006 -12 and Catalonia Government through SGR 2009 -0323.
dc.format.extent 19
dc.format.mimetype application/pdf
dc.language.iso eng
dc.publisher Elsevier
dc.rights © Elsevier
dc.rights Atribución-NoComercial-SinDerivadas 3.0 España
dc.rights.uri http://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.subject.other process intensification
dc.subject.other microreactor
dc.subject.other high temperature synthetic processes
dc.subject.other quantum dots
dc.subject.other on-line syntheses
dc.subject.other thermal/microfluidic characterization
dc.title Design, fabrication and characterization of microreactors for high temperature syntheses
dc.type article
dc.subject.eciencia Materiales
dc.identifier.doi https://doi.org/10.1016/j.cej.2012.09.101
dc.rights.accessRights openAccess
dc.relation.projectID Gobierno de España. CTQ2009-12128
dc.relation.projectID Gobierno de España. CSD2006
dc.type.version acceptedVersion
dc.identifier.publicationfirstpage 432
dc.identifier.publicationlastpage 441
dc.identifier.publicationtitle Chemical engineering journal
dc.identifier.publicationvolume 211-212
dc.identifier.uxxi AR/0000021083
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