Confocal microscopy study of phase morphology evolution in epoxy/polysiloxane thermosets

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dc.contributor.author Cabanelas Valcárcel, Juan Carlos
dc.contributor.author Serrano Prieto, Berna
dc.contributor.author Gonzalez Gonzalez, Maria
dc.contributor.author Baselga Llidó, Juan
dc.date.accessioned 2017-11-22T11:47:13Z
dc.date.available 2017-11-22T11:47:13Z
dc.date.issued 2005-08-08
dc.identifier.bibliographicCitation Cabanelas, J. C., Serrano, B., G. González, M. & Baselga, J. (2005). Confocal microscopy study of phase morphology evolution in epoxy/polysiloxane thermosets. Polymer, 46 (17), pp. 6633-6639.
dc.identifier.issn 0032-3861
dc.identifier.uri http://hdl.handle.net/10016/25930
dc.description.abstract The morphology of stoichiometric initially immiscible reactive blends of DGEBA epoxy resin and poly(3-aminopropylmethylsiloxane) has been characterized by laser scanning confocal microscopy. Observations were done on samples cured isothermally at different curing temperatures in the range 20–120 °C as well as in situ and in real time at 60 °C. Three different processes were revealed: coalescence, which occurs primarily at very low conversion, diffusion of DGEBA through polysiloxane-rich domains and chemical reaction, which occurs at the interphase between both phases. The interphase-thickness and compositional gradients were characterized by laser scanning confocal microscopy (LSCM). Results show that as curing temperature increases within the studied range, the material becomes more homogeneous although the interphase thickness remains almost constant.
dc.description.sponsorship The authors would like to acknowledge the financial support from projects Epoxsil (MAT2000-0391-P4-02) and Fibrodont (MAT2001-0677-P3).
dc.format.extent 7
dc.format.mimetype application/pdf
dc.language.iso eng
dc.publisher Elsevier
dc.rights © Elsevier, 2005
dc.rights Atribución-NoComercial-SinDerivadas 3.0 España
dc.rights.uri http://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.subject.other Reactive compatibilization
dc.subject.other Epoxy resin
dc.subject.other Confocal microscopy
dc.title Confocal microscopy study of phase morphology evolution in epoxy/polysiloxane thermosets
dc.type article
dc.subject.eciencia Materiales
dc.subject.eciencia Química
dc.identifier.doi https://doi.org/10.1016/j.polymer.2005.05.017
dc.rights.accessRights openAccess
dc.relation.projectID Comunidad de Madrid. MAT2000-0391-P4-02
dc.relation.projectID Comunidad de Madrid. MAT2001-0677-P3
dc.type.version acceptedVersion
dc.identifier.publicationfirstpage 6633
dc.identifier.publicationissue 17
dc.identifier.publicationlastpage 6639
dc.identifier.publicationtitle Polymer
dc.identifier.publicationvolume 46
dc.identifier.uxxi AR/0000020515
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