Modelling auto-acceleration in DGEBA/diamine systems

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dc.contributor.author González González, María
dc.contributor.author Kindelan Segura, Manuel
dc.contributor.author Cabanelas Valcárcel, Juan Carlos
dc.contributor.author Baselga Llidó, Juan
dc.date.accessioned 2017-11-16T11:08:23Z
dc.date.available 2017-11-16T11:08:23Z
dc.date.issued 2003-10
dc.identifier.bibliographicCitation González, M., Kindelán, M., Cabanelas, J. C. & Baselga, J. (2003). Modelling auto-acceleration in DGEBA/diamine systems. Macromolecular Symposia. Functional Networks and Gels, 200 (1), pp. 111-120.
dc.identifier.issn 1521-3900
dc.identifier.uri http://hdl.handle.net/10016/25854
dc.description.abstract Curing of epoxy resins with aliphatic diamines at low temperatures deviates from the 4EQ mechanism (catalytic and non-catalytic dual path) at relatively low conversions, far from vitrification. Although the Horie mechanism relies on a third order reaction it is possible a more realistic approach to epoxy curing kinetics if a detailed analysis of auto-acceleration is made. A single parameter dependent only on the nature of the amine is proposed.
dc.description.sponsorship Authors gratefully acknowledge to CAM (Pricit) and to project Epoxsil (MAT2000-0391-P4-02) for financial support.
dc.format.extent 10
dc.format.mimetype application/pdf
dc.language.iso eng
dc.publisher WILEY-VCH Verlag GmbH
dc.rights © Wiley, 2003
dc.subject.other Amine
dc.subject.other Auto-acceleration
dc.subject.other Diamine systems
dc.subject.other Epoxy-amine kinetics
dc.subject.other Epoxy resin
dc.title Modelling auto-acceleration in DGEBA/diamine systems
dc.type article
dc.subject.eciencia Materiales
dc.subject.eciencia Química
dc.identifier.doi https://doi.org/10.1002/10.1002/masy.200351011
dc.rights.accessRights openAccess
dc.relation.projectID Comunidad de Madrid. MAT2000-0391-P4-02
dc.type.version acceptedVersion
dc.identifier.publicationfirstpage 111
dc.identifier.publicationissue 1
dc.identifier.publicationlastpage 120
dc.identifier.publicationtitle Macromolecular Symposia. Special Issue: Functional Networks and Gels
dc.identifier.publicationvolume 200
dc.identifier.uxxi AR/0000003404
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