dc.contributor.author |
González González, María |
dc.contributor.author |
Kindelan Segura, Manuel
|
dc.contributor.author |
Cabanelas Valcárcel, Juan Carlos
|
dc.contributor.author |
Baselga Llidó, Juan
|
dc.date.accessioned |
2017-11-16T11:08:23Z |
dc.date.available |
2017-11-16T11:08:23Z |
dc.date.issued |
2003-10 |
dc.identifier.bibliographicCitation |
González, M., Kindelán, M., Cabanelas, J. C. & Baselga, J. (2003). Modelling auto-acceleration in DGEBA/diamine systems. Macromolecular Symposia. Functional Networks and Gels, 200 (1), pp. 111-120. |
dc.identifier.issn |
1521-3900 |
dc.identifier.uri |
http://hdl.handle.net/10016/25854 |
dc.description.abstract |
Curing of epoxy resins with aliphatic diamines at low temperatures deviates from the 4EQ mechanism (catalytic and non-catalytic dual path) at relatively low conversions, far from vitrification. Although the Horie mechanism relies on a third order reaction it is possible a more realistic approach to epoxy curing kinetics if a detailed analysis of auto-acceleration is made. A single parameter dependent only on the nature of the amine is proposed. |
dc.description.sponsorship |
Authors gratefully acknowledge to CAM (Pricit) and to project Epoxsil (MAT2000-0391-P4-02) for financial support. |
dc.format.extent |
10 |
dc.format.mimetype |
application/pdf |
dc.language.iso |
eng |
dc.publisher |
WILEY-VCH Verlag GmbH |
dc.rights |
© Wiley, 2003 |
dc.subject.other |
Amine |
dc.subject.other |
Auto-acceleration |
dc.subject.other |
Diamine systems |
dc.subject.other |
Epoxy-amine kinetics |
dc.subject.other |
Epoxy resin |
dc.title |
Modelling auto-acceleration in DGEBA/diamine systems |
dc.type |
article |
dc.subject.eciencia |
Materiales |
dc.subject.eciencia |
Química |
dc.identifier.doi |
https://doi.org/10.1002/10.1002/masy.200351011 |
dc.rights.accessRights |
openAccess |
dc.relation.projectID |
Comunidad de Madrid. MAT2000-0391-P4-02 |
dc.type.version |
acceptedVersion |
dc.identifier.publicationfirstpage |
111 |
dc.identifier.publicationissue |
1 |
dc.identifier.publicationlastpage |
120 |
dc.identifier.publicationtitle |
Macromolecular Symposia. Special Issue: Functional Networks and Gels |
dc.identifier.publicationvolume |
200 |
dc.identifier.uxxi |
AR/0000003404 |
dc.affiliation.dpto |
UC3M. Departamento de Ciencia e Ingeniería de Materiales e Ingeniería Química |
dc.affiliation.dpto |
UC3M. Departamento de Matemáticas |
dc.affiliation.grupoinv |
UC3M. Grupo de Investigación: Polímeros y Composites |
dc.affiliation.grupoinv |
UC3M. Grupo de Investigación: Modelización, Simulación Numérica y Matemática Industrial |