Publication: Layer shape LiFePO4 obtained by powder extrusion molding as solid boosters for ferro/ferricyanide catholyte in semisolid redox flow battery: Effect of porosity and shape
dc.affiliation.dpto | UC3M. Departamento de Ciencia e Ingeniería de Materiales e Ingeniería Química | es |
dc.affiliation.grupoinv | UC3M. Grupo de Investigación: Síntesis y Procesado de Materiales | es |
dc.contributor.author | Vivo Vilches, José Francisco | |
dc.contributor.author | Vázquez Navalmoral, Álvaro | |
dc.contributor.author | Torre Gamarra, Carmen de la | |
dc.contributor.author | Cebollada, Jesús | |
dc.contributor.author | Varez, Alejandro | |
dc.contributor.author | Levenfeld Laredo, Belén | |
dc.contributor.funder | Comunidad de Madrid | es |
dc.contributor.funder | European Commission | en |
dc.contributor.funder | Ministerio de Ciencia e Innovación (España) | es |
dc.contributor.funder | Universidad Carlos III de Madrid | es |
dc.date.accessioned | 2023-04-13T08:24:33Z | |
dc.date.available | 2023-04-13T08:24:33Z | |
dc.date.issued | 2022-07 | |
dc.description.abstract | Powder extrusion molding is proposed to fabricate ceramic LiFePO4 layers (0.5-1.0 mm thickness) as solid booster for ferricyanide electrolyte in semisolid redox flow battery. In some extruded layers, the binder is partially decomposed, while in others it is completely removed and, afterwards, the material is sintered, so materials with different porosity and dimensions are obtained. After characterizing the materials, the kinetics for the reaction with ferricyanide is evaluated, being the binder-less materials the ones which react faster and reach larger degrees of oxidation. For the material with 1.0 mm thick comparable results to the ones already published are obtained (69 % capacity for LiFePO4 compared to the theoretical value). In the case of the 0.5 mm thick sintered solid, an outstanding performance is achieved, reaching almost the theoretical capacity (94 %) with a very high coulombic efficiency (>99 %) at 1 mA cm-2, results that were only obtained at much lower current densities in previous works. | en |
dc.description.sponsorship | The author Jose F. Vivo-Vilches acknowledges support from the CONEX-Plus programme funded by Universidad CarlosIII de Madrid and the European Union's Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement No. 801538.The authors also thank the Agencia Española de Investigación/Fondo Europeo de Desarrollo Regional (FEDER/UE) for funding the project PID2019-106662RBC43.This work has also been supported by Comunidad de Madrid (Spain) though two project: multiannual agreement with UC3M ("Excelencia para el Profesorado Universitario"-EPUC3M04) -Fifth regional research plan 2016-2020, and DROMADER-CM (Y2020/NMT6584). | en |
dc.format.extent | 8 | |
dc.identifier.bibliographicCitation | Vivo-Vilches, J. F., Vázquez-Navalmoral, Á., De La Torre-Gamarra, C., Cebollada, J., Várez, A., & Levenfeld, B. (2022). Layer shape LiFePO4 obtained by Powder Extrusion Molding as solid boosters for ferro/ferricyanide catholyte in semisolid redox flow battery: effect of porosity and shape. Batteries & supercaps, 5(7), e202200050. | en |
dc.identifier.doi | https://doi.org/10.1002/batt.202200050 | |
dc.identifier.issn | 2566-6223 | |
dc.identifier.publicationfirstpage | 1 | |
dc.identifier.publicationissue | 7, e202200050 | |
dc.identifier.publicationlastpage | 8 | |
dc.identifier.publicationtitle | Batteries and Supercaps | en |
dc.identifier.publicationvolume | 5 | |
dc.identifier.uri | https://hdl.handle.net/10016/37044 | |
dc.identifier.uxxi | AR/0000031411 | |
dc.language.iso | eng | |
dc.publisher | Wiley | en |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/COFUND-GA-2017-801538 | |
dc.relation.projectID | Internacional. COFUND-GA-2017-801538 | es |
dc.relation.projectID | Gobierno de España. PID2019-106662RB-C43 | es |
dc.relation.projectID | Comunidad de Madrid. EPUC3M04 | es |
dc.relation.projectID | Comunidad de Madrid. Y2020/NMT6584 | es |
dc.relation.projectID | AT-2022 | es |
dc.rights | © 2022 The Authors. | en |
dc.rights | Atribución 3.0 España | * |
dc.rights.accessRights | open access | en |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.subject.eciencia | Electrónica | es |
dc.subject.eciencia | Energías Renovables | es |
dc.subject.eciencia | Ingeniería Industrial | es |
dc.subject.eciencia | Materiales | es |
dc.subject.eciencia | Química | es |
dc.subject.other | Energy storage | en |
dc.subject.other | Powder extrusion molding | en |
dc.subject.other | Redox flow batteries | en |
dc.subject.other | Solid boosters | en |
dc.title | Layer shape LiFePO4 obtained by powder extrusion molding as solid boosters for ferro/ferricyanide catholyte in semisolid redox flow battery: Effect of porosity and shape | en |
dc.type | research article | * |
dc.type.hasVersion | VoR | * |
dspace.entity.type | Publication |
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