Publication:
High performance NASICON ceramic electrolytes produced by tape-casting and low-temperature hot-pressing: Towards sustainable all-solid-state sodium batteries operating at room temperature

dc.affiliation.dptoUC3M. Departamento de Ciencia e Ingeniería de Materiales e Ingeniería Químicaes
dc.affiliation.grupoinvUC3M. Grupo de Investigación: Síntesis y Procesado de Materialeses
dc.contributor.authorNaranjo Balseca, Johanna-Monserrath
dc.contributor.authorMartínez Cisneros, Cynthia Susana
dc.contributor.authorPandit, Bidhan
dc.contributor.authorLumbier Álvarez, Alejandro
dc.contributor.funderAgencia Estatal de Investigación (España)es
dc.contributor.funderComunidad de Madrides
dc.contributor.funderEuropean Commissionen
dc.contributor.funderUniversidad Carlos III de Madrides
dc.date.accessioned2023-12-15T13:18:01Z
dc.date.available2023-12-15T13:18:01Z
dc.date.issued2023-09
dc.description.abstractIn this work, we propose a processing methodology, based on the combination of tape-casting and low temperature hot-pressing, to develop ceramic NASICON electrolytes with formula Na3.16Zr1.84Y0.16Si2PO12 towards the attainment of solid-state sodium batteries operating at room temperature. Solid-state NASICON electrolytes with very good mechanical properties and high ionic conductivity are successfully tested in terms of electrochemical behavior by using the cell configuration: Na/NASICON/FePO4. Following charge-discharge cycles, an unusual redox pair of FePO4 is found, indicating that the all-solid-state battery with the Na metal anode may be effectively operated at room temperature. At a charge/discharge current density of C/20, the solid-state battery has an initial reversible discharge capacity of 85 mAh/g. Because of its relatively high ionic conductivity and thermostability, when in contact with the Na anode and the FePO4 cathode, the NASICON ceramic electrolyte is a viable option for attaining reliable, safer and sustainable all-solid-state batteries operating at room temperature.en
dc.description.sponsorshipThe authors would like to thank the Agencia Española de Investigación/Fondo Europeo de Desarrollo Regional (FEDER/UE) for funding the projects PID2019-106662RBC43. This work has been supported by the Madrid Government (Comunidad de Madrid-Spain) through three projects: 1) the Multiannual Agreement with UC3M (“Fostering Young Doctors Research”, CIRENAICA-CM-UC3M), and in the context of the VPRICIT (Research and Technological Innovation Regional Programme); 2) the Multiannual agreement with UC3M (“Excelencia para el Profesorado Universitario” - EPUC3M04) - Fifth regional research plan 2016–2020; 3) DROMADER-CM (Y2020/NMT6584). B.P. also acknowledge the CONEX-Plus programme funded by Universidad Carlos III de Madrid (UC3M) and the European Commission through the Marie-Sklodowska Curie COFUND Action (Grant Agreement No 801538). Funding for APC: Universidad Carlos III de Madrid (Read & Publish Agreement CRUE-CSIC 2023).en
dc.format.extent11
dc.identifier.bibliographicCitationNaranjo-Balseca, J. M., Martínez-Cisneros, C. S., Pandit, B., & Várez, A. (2023). High performance NASICON ceramic electrolytes produced by tape-casting and low temperature hot-pressing: towards sustainable all-solid-state sodium batteries operating at room temperature. Journal of the European Ceramic Society, 43(11), 4826-4836.en
dc.identifier.doihttps://doi.org/10.1016/j.jeurceramsoc.2023.04.008
dc.identifier.issn0955-2219
dc.identifier.publicationfirstpage4826
dc.identifier.publicationissue11
dc.identifier.publicationlastpage4836
dc.identifier.publicationtitleJournal of the European Ceramic Societyen
dc.identifier.publicationvolume43
dc.identifier.urihttps://hdl.handle.net/10016/39103
dc.identifier.uxxiAR/0000033362
dc.language.isoengen
dc.publisherElsevieren
dc.relation.projectIDInternacional. COFUND-GA-2017-801538es
dc.relation.projectIDGobierno de España. PID2019-106662RB-C43es
dc.relation.projectIDComunidad de Madrid. CIRENAICA-CM-UC3Mes
dc.relation.projectIDComunidad de Madrid. Y2020/NMT6584es
dc.rights© 2023 The Authors.en
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.accessRightsopen accessen
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subject.ecienciaIngeniería Industriales
dc.subject.ecienciaMaterialeses
dc.subject.ecienciaQuímicaes
dc.subject.otherAll-solid-state batteriesen
dc.subject.otherSodium-ion batteryen
dc.subject.otherNASICON electrolytesen
dc.titleHigh performance NASICON ceramic electrolytes produced by tape-casting and low-temperature hot-pressing: Towards sustainable all-solid-state sodium batteries operating at room temperatureen
dc.typeresearch article*
dc.type.hasVersionVoR*
dspace.entity.typePublication
Files
Original bundle
Now showing 1 - 2 of 2
Loading...
Thumbnail Image
Name:
High-performance_JECS_2023.pdf
Size:
5.27 MB
Format:
Adobe Portable Document Format
Loading...
Thumbnail Image
Name:
High-performance_JECS_2023_SI.pdf
Size:
251.26 KB
Format:
Adobe Portable Document Format